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Title: Preparation and Molecular Structure of a Cyclopentyl-Substituted Cage Hexasilsesquioxane T6 (T = cyclopentyl-SiO1.5) Starting from the Corresponding Silanetriol
Authors: Kahr, JürgenBelaj, FerdinandPietschnig, Rudolf
???metadata.dc.subject.ddc???: 540 - Chemie (Chemistry and allied sciences)
Issue Date: 4-Oct-2017
Citation: In: Inorganics. - Basel : MDPI. - 2017, 5(4), 66, 1-8
Abstract: Cyclopentyl substituted silanetriol can be prepared and isolated. Its condensation yields the corresponding disiloxanetetrol as a primary condensation product. Further condensation leads to the hexameric polyhedral silsesquioxane cage T6. The latter has been mentioned in the literature before however, lacking structural data. All compounds have been characterized with multinuclear NMR spectroscopy and, in addition, the molecular structures have been determined in the case of the disiloxanetetrol and the hexasilsesquioxane via single crystal X-ray diffraction.
URI: urn:nbn:de:hebis:34-2018020254389
additional URI: doi:10.3390/inorganics5040066OA-GEF
ISSN: 2304-6740
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