Datum
2022-04-27Autor
Winczewski, Jędrzej PiotrHerrera, ManuelCabriel, ClémentIzeddin, IgnacioGabel, StefanMerle, BenoitSusarrey Arce, ArturoGardeniers, Han J. G. E.Schlagwort
600 Technik 660 Chemische Verfahrenstechnik, Technische Chemie Rapid Prototyping <Fertigung>EuropiumLumineszenzLithografieZirkoniumdioxidMetadata
Zur Langanzeige
Aufsatz
Additive Manufacturing of 3D Luminescent ZrO2:Eu3+ Architectures
Zusammenfassung
Implementation of more refined structures at the nano to microscale is expected to advance applications in optics and photonics. This work presents the additive manufacturing of 3D luminescent microarchitectures emitting light in the visible range. A tailor-made organo-metallic resin suitable for two-photon lithography is developed, which upon thermal treatment in an oxygen-rich atmosphere allows the creation of silicon-free tetragonal (t-) and monoclinic (m-) ZrO₂. The approach is unique because the tailor-made Zr-resin is different from what is achieved in other reported approaches based on sol−gel resins. The Zr-resin is compatible with the Eu-rich dopant, a luminescent activator, which enables to tune the optical properties of the ZrO₂ structures upon annealing. The emission characteristics of the Eu-doped ZrO₂ microstructures are investigated in detail with cathodoluminescence and compared with the intrinsic optical properties of the ZrO₂. The hosted Eu has an orange−red emission showcased using fluorescence microscopy. The presented structuring technology provides a new platform for the future development of 3D luminescent devices.
Zitierform
In: Advanced Engineering Materials Volume 10 / Issue 12 (2022-04-27) eissn:1527-2648Förderhinweis
European Research Council (ERC) under the Horizon 2020 research and innovation programme of the European Union. Grant Numbers: 742004, 949626; University of California Institute for Mexico and the United States. Grant Number: CN19137; CONACYT. Grant Number: 284667; University of TwenteZitieren
@article{doi:10.17170/kobra-202307278515,
author={Winczewski, Jędrzej Piotr and Herrera, Manuel and Cabriel, Clément and Izeddin, Ignacio and Gabel, Stefan and Merle, Benoit and Susarrey Arce, Arturo and Gardeniers, Han J. G. E.},
title={Additive Manufacturing of 3D Luminescent ZrO2:Eu3+ Architectures},
journal={Advanced Engineering Materials},
year={2022}
}
0500 Oax 0501 Text $btxt$2rdacontent 0502 Computermedien $bc$2rdacarrier 1100 2022$n2022 1500 1/eng 2050 ##0##http://hdl.handle.net/123456789/14947 3000 Winczewski, Jędrzej Piotr 3010 Herrera, Manuel 3010 Cabriel, Clément 3010 Izeddin, Ignacio 3010 Gabel, Stefan 3010 Merle, Benoit 3010 Susarrey Arce, Arturo 3010 Gardeniers, Han J. G. E. 4000 Additive Manufacturing of 3D Luminescent ZrO2:Eu3+ Architectures / Winczewski, Jędrzej Piotr 4030 4060 Online-Ressource 4085 ##0##=u http://nbn-resolving.de/http://hdl.handle.net/123456789/14947=x R 4204 \$dAufsatz 4170 5550 {{Rapid Prototyping <Fertigung>}} 5550 {{Europium}} 5550 {{Lumineszenz}} 5550 {{Lithografie}} 5550 {{Zirkoniumdioxid}} 7136 ##0##http://hdl.handle.net/123456789/14947
2023-07-28T16:01:52Z 2023-07-28T16:01:52Z 2022-04-27 doi:10.17170/kobra-202307278515 http://hdl.handle.net/123456789/14947 European Research Council (ERC) under the Horizon 2020 research and innovation programme of the European Union. Grant Numbers: 742004, 949626; University of California Institute for Mexico and the United States. Grant Number: CN19137; CONACYT. Grant Number: 284667; University of Twente eng Namensnennung 4.0 International http://creativecommons.org/licenses/by/4.0/ additive manufacturing europium luminescence two-photon lithography zirconia 600 660 Additive Manufacturing of 3D Luminescent ZrO2:Eu3+ Architectures Aufsatz Implementation of more refined structures at the nano to microscale is expected to advance applications in optics and photonics. This work presents the additive manufacturing of 3D luminescent microarchitectures emitting light in the visible range. A tailor-made organo-metallic resin suitable for two-photon lithography is developed, which upon thermal treatment in an oxygen-rich atmosphere allows the creation of silicon-free tetragonal (t-) and monoclinic (m-) ZrO₂. The approach is unique because the tailor-made Zr-resin is different from what is achieved in other reported approaches based on sol−gel resins. The Zr-resin is compatible with the Eu-rich dopant, a luminescent activator, which enables to tune the optical properties of the ZrO₂ structures upon annealing. The emission characteristics of the Eu-doped ZrO₂ microstructures are investigated in detail with cathodoluminescence and compared with the intrinsic optical properties of the ZrO₂. The hosted Eu has an orange−red emission showcased using fluorescence microscopy. The presented structuring technology provides a new platform for the future development of 3D luminescent devices. open access Winczewski, Jędrzej Piotr Herrera, Manuel Cabriel, Clément Izeddin, Ignacio Gabel, Stefan Merle, Benoit Susarrey Arce, Arturo Gardeniers, Han J. G. E. doi:10.1002/adom.202102758 742004, 949626, CN19137, 284667 Rapid Prototyping <Fertigung> Europium Lumineszenz Lithografie Zirkoniumdioxid publishedVersion eissn:1527-2648 Issue 12 Advanced Engineering Materials Volume 10 false 2102758
Die folgenden Lizenzbestimmungen sind mit dieser Ressource verbunden: